On the Kabbalah and its Symbolism would be the best place to start with Scholem, IMHO.
As for learning Hebrew, run a Google search. It will take some wading, since most of the results point to either books or classes. You could always get
Hebrew for Dummies (IMG:
style_emoticons/default/wink.gif) Personally, I started with a text called
HaYesod which wasn't too expensive. Check the libraries also!